WebCinchoninic acid derivatives involved base catalyzed condensation of 5-(trifluoromethoxy)isatin (1) and enolizable 1-(pyrazin-2-yl)ethanone (2) commonly known as the Pfitzinger reaction gave 2-(pyrazin-2-yl)-6-(trifluoromethoxy)quinoline-4-carboxylic acid (3) Cinchoninic acid, which upon coupling with different Web2-Trifluoromethyl cinchoninic acid, and substituted 2-trifluoromethyl cinchoninic acids, are known plant growth regulating materials. Such compounds can be prepared, as disclosed by B. M. Pinder and A. Burger (J. Med. Chem, 11, pp 267-269 (1968)), by condensation of aniline, or a substituted aniline, with ethyl 4,4,4-trifluoroacetoacetate in the presence of …
US4267333A - Preparation of 2-trifluoromethyl cinchoninic acids ...
WebNov 1, 1998 · The cinchoninic acid derivative brequinar (quinoline carboxylic acid [11]), which originally was discovered as a cytostatic agent with a strong effect on … WebJan 3, 2000 · Despite this high conservation, kinetic experiments gave evidence for a different susceptibility of the rat and human DHOdehase to the cinchoninic acid brequinar and the isoxazol derivative leflunomide [16]. 1,4-Naphthoquinone derivatives, such as lawsone, lapachol, DCL and atovaquone were reported to interfere with the oxidation of ... philly cheese steak stuffed pepper recipe
Electronic absorption and fluorescence of cinchophen, cinchoninic acid ...
Web4-Quinolinecarboxylic acid was used in the coupling reaction with diamine linker. A 4-quinolinecarboxylic acid analogue, brequinar sodium was used to inhibit dihydroorotate dehydrogenase and the de novo biosynthesis of pyrimidine. WebThe pH and Hammett acidity dependences of the absorption and fluorescence spectra of cinchoninic acid (quinoline-4-carboxylic acid), cinchophen (2-phenylquinoline-4-carboxylic acid) and their methyl esters, were studied. The predominant uncharged ground-state species derived from the free acids are zwitterions. Prototropic equilibria are too ... tsars family